期刊
ORGANIC LETTERS
卷 15, 期 8, 页码 1966-1969出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol400638q
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资金
- National Research Foundation Singapore [NRF-RF2009-05]
- Nanyang Technological University
We report here a palladium(II)-catalyzed oxidative cyclization reaction of N-allylimines derived from methyl ketones, typically acetophenones, affording pyrrole derivatives at room temperature under oxygen atmosphere. The reaction likely proceeds through alpha-palladation of the imine followed by olefin migratory insertion and beta-hydride elimination, thus representing a new example of aerobic dehydrogenative Heck cyclization.
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