4.8 Article

Enantioselective Oxidation of 1,2-Diols with Quinine-Derived Urea Organocatalyst

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ORGANIC LETTERS
卷 16, 期 1, 页码 208-211

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AMER CHEMICAL SOC
DOI: 10.1021/ol4032045

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  1. Singapore National Research Foundation (NRF Fellowship)
  2. National University of Singapore

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Quinine-derived urea has been identified as a highly efficient organocatalyst for the enantioselective oxidation of 1,2-diols using bromination reagents as the oxidant. This simple procedure utilizes readily available reagents and operates at ambient temperature to yield a wide range of a-hydroxy ketones in good yield (up to 94%) and excellent enantioselectivity (up to 95% ee).

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