期刊
ORGANIC LETTERS
卷 15, 期 13, 页码 3444-3447出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401518c
关键词
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资金
- Duke University
- Duke University Pharmacological Sciences Training Program
- Burroughs Wellcome Endowment
A new approach to access o-haloaminoarenes has been achieved by insertion of arynes into a nitrogen-halide bond (N-X). This transition-metal-free transformation displays a broad substrate scope of arynes, good compatibility with functional groups, and high regioselectivity. Representative transformations of the o-haloaminoarenes are described to highlight their utility for rapid access to diversely functionalized a minoarene derivatives.
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