期刊
ORGANIC LETTERS
卷 15, 期 21, 页码 5602-5605出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol402859k
关键词
-
资金
- National Institutes of Health [GM46059]
- National Science Foundation [2010094243, CHE 980861, DBI 9729592]
- Amgen
The stable Pd(0) species [(1,5-cyclooctadiene)(L.Pd)(2)] (L = AdBrettPhos) has been prepared and successfully evaluated as a precatalyst for the fluorination of aryl triflates derived from biologically active and heteroaryl phenols, challenging substrates for our previously reported catalyst system. Additionally, this precatalyst activates at room temperature under neutral conditions, generates 1,5-cyclooctadiene as the only byproduct, and leads to overall cleaner reaction profiles.
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