期刊
ORGANIC LETTERS
卷 15, 期 3, 页码 550-553出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol303366u
关键词
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资金
- NSFC [20802029, 21172096]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars
- Fundamental Research Funds for the Central Universities [lzujbky-2012-57]
- IRT1138 Program
- 111 Project of MoE
A Ni(0)-catalyzed intermolecular cross-coupling of various functionalized thiols and aryl Iodides has been developed and successfully extended to less explored intramolecular versions, where thioacetates could also be utilized as the strategic surrogate. Air-stable precatalysts, very mild conditions, and an easy protocol allow rapid access to medicinally useful aryl thioethers, as demonstrated in the facile synthesis of (+/-)-chuangxinmycin as a key step.
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