期刊
ORGANIC LETTERS
卷 15, 期 11, 页码 2604-2607出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol400773k
关键词
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资金
- National Natural Science Foundation of China [21172076, 20932002]
- National Basic Research Program of China (973 Program) [2011CB808600]
- Changjiang Scholars and Innovation Team Project of Ministry of Education
- Guangdong Natural Science Foundation [10351064101000000, S2012040007088]
- China Post-doctoral Science Foundation [2012150673]
- Fundamental Research Funds for the Central Universities [2012ZP0003, 2012ZB0011]
A metal-free process for the synthesis of 2-aminobenzothiazoles from cyclohexanones and thioureas has been developed using catalytic iodine and molecular oxygen as the oxidant under mild conditions. Various 2-aminobenzothiazoles, 2-aminonaphtho[2,1-d]thiazoles, and 2-aminonaphtho[1,2-d]thiazoles were prepared via this method in satisfactory yields.
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