期刊
ORGANIC LETTERS
卷 15, 期 17, 页码 4548-4551出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol402106x
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资金
- Deutsche Forschungsgemeinschaft (DFG)
Radical azidooxygenation of various alkenes is described. A readily prepared N-3-iodine(III) reagent acts as a clean N-3-radical precursor. Radical generation is achieved with TEMPONa acting as a mild organic reducing reagent. The C-radical generated after N-3-radical addition is efficiently trapped by in situ generated TEMPO. Yields are good to excellent, and for cyclic systems azidooxygenation occurs with excellent diastereoselectivity.
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