期刊
ORGANIC LETTERS
卷 15, 期 24, 页码 6198-6201出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403039b
关键词
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资金
- CNRS
- Universite de Strasbourg
- ANR [07-PCVI-016]
The n-Bu3P organocatalyzed reaction of cycloalkanones, i.e., cyclopentanones or 1,3-cyclopentanediones tethered to actived olefins, afforded selectively and in high yields three different types of products: bicyclo[3.2.1]octanones, mixed acetals, and Morita-Baylis-Hillman products. The progress of the reaction was closely related to the reaction medium and to the length of the tether located between the cyclopentanone (-dione) and the activated olefin.
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