期刊
ORGANIC LETTERS
卷 15, 期 19, 页码 4976-4979出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol402236z
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资金
- Gobierno de Espana MINECO [CTQ2011-23014]
- Generalitat de Catalunya DURSI [2009SGR6868]
- ICIQ Foundation
- MINECO
- ICREA Funding Source: Custom
Thermally and in nonprotic media N,N-climethyl-2-propyn-1-amine N-oxide undergoes two consecutive sigmatropic rearrangements affording propenal. Two molecular containers capable of the quantitative inclusion/encapsulation of the N-oxide are described. The N-oxide becomes kinetically stabilized when included in the containers. The relationship between the observed kinetic stabilization of the N-oxide and the thermodynamic and kinetic stability of its inclusion complexes is explained and modeled.
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