期刊
ORGANIC LETTERS
卷 15, 期 15, 页码 4026-4029出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401839e
关键词
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资金
- Florida State University
- National Science Foundation [NSF-CHE 1300722]
- Vietnam Education Foundation (VEF Fellowship)
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1300722] Funding Source: National Science Foundation
A tandem process provides high-value 1,6-enynes that are otherwise difficult to prepare. Two base-mediated reactions-fragmentation and olefination-are executed in a coordinated manner that is overall more efficient than either reaction on its own. The 1,6-enynes can be strategically employed in conjunction with carbocyclization to deliver important targets, as noted for reported syntheses of hirsutene and illudol.
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