期刊
ORGANIC LETTERS
卷 15, 期 23, 页码 5990-5993出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol402871f
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资金
- National Science Foundation of China [21202049]
- Recruitment Program of Global Experts
- Huaqiao University
A Cu(II)-catalyzed oxidative decarboxylative synthesis of 2-aryl benzothiazole from phenylacetic acids and alpha-hydroxyphenylacetic acids has been developed. This reaction proceeds via Cu(II)-catalyzed decarboxylation, C-H bond oxidation, ring-opening, and condensation steps in a one-pot protocol with dioxygen as the sole terminal oxidant. Various functional groups were tolerated under standard conditions, and isolated yields were as high as 95%.
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