期刊
ORGANIC LETTERS
卷 15, 期 15, 页码 4010-4013出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401815n
关键词
-
资金
- National Science Foundation [CHE-1262479]
Hypervalent iodine catalyzed oxidation of aldoximes using ozone as a terminal oxidant generates nitrile oxides, which react with alkenes and alkynes to give the corresponding isoxazolines and isoxazoles in moderate to good yields. This reaction involves active hypervalent iodine species formed in situ from catalytic iodoarene and oxone in the presence of hexafluoroisopropanol in aqueous methanol solution.
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