期刊
ORGANIC LETTERS
卷 15, 期 13, 页码 3472-3475出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol401554y
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资金
- Royal Society
- European Research Council under the European Union [279850]
- European Research Council (ERC) [279850] Funding Source: European Research Council (ERC)
Telescoped and one-pot olefination/asymmetric functionalization approaches to disubstituted pyrrolidines (dr up to 99:1, up to 99% ee) have been developed using commercially available tetramisole (0.1 to 5 mol %). Using OTMS-quinidine as the Lewis base gives preferential access to an anti-configured pyrrolidine in high enantioselectivity.
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