期刊
ORGANIC LETTERS
卷 15, 期 9, 页码 2108-2111出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol4001476
关键词
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资金
- Slovenian Research Agency [P1-0134, PR-03767-1, BI-US/12-13-004]
- Human Resources Development and Scholarship fund [11012-1712012-7]
- European Regional Development Found [OP 13.1.1.02.0005]
- UNF
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1126265] Funding Source: National Science Foundation
Novel multifunctional ionic liquids (ILs) are generated by addition of HBr or HCl to alkylammonium nitrates ([RNH3+] [NO3-]) and to 3-methyl-1-(butyl-4-sulfonyl)imidazolium nitrate ([BMIM(SO3H)][NO3]). The resulting [RNH3+] [NO3-]/HX and mono (3-methyl-1-(butyl-4-sulfonyl)imidazolium) monohalogenide mononitrate ([BMIM(SO3H)][NO3)(x)(X)(y)] (X = Br, Cl)) systems act as solvent and promoter for aerobic oxidative halogenation of arenes under mild conditions in high yields that can be repeated over several cycles.
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