期刊
ORGANIC LETTERS
卷 15, 期 6, 页码 1218-1221出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol400134d
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资金
- NIGMS [P50 GM069721]
Macrocyclic (E)-alkenylsiloxanes, obtained from E-selective ring-closing metathesis reactions, can be converted to the corresponding (Z)-alkenyl bromides and (E)-alkenyl iodides allowing access to both E- and Z-trisubstituted macrocyclic alkenes. The reaction conditions and substrate scope of these stereoselective transformations are explored.
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