期刊
ORGANIC LETTERS
卷 15, 期 18, 页码 4846-4849出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol4022589
关键词
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资金
- National Natural Science Foundation of China [21202207, J1103305]
- Research Fund for Guangzhou Peal River New Star of Science and Technology [2013J2200017]
- Beijing National Laboratory of Molecular Sciences (BNLMS)
A mild and efficient method for the synthesis of 6-(trifluoromethyl)phenanthridines through oxidative cyclization of 2-isocyanobiphenyls with CF3SiMe3 under metal-free conditions was developed. The reaction allows the direct formation of C-CF3 bonds and rapid access to phenanthridine ring systems in one catalytic cycle.
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