期刊
ORGANIC LETTERS
卷 15, 期 24, 页码 6210-6213出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403059z
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资金
- National Basic Research Program of China [973-2011CB808700]
- National Nature Science Foundation of China [20923005, 2125210, 21202185, 21121062]
- Science and Technology Commission of the Shanghai Municipality [11JC1415000]
- CAS/SAFEA International Partnership Program for Creative Research Teams
A cascade approach to 1-(trifluoromethyl)-4-fluoro-1,2-dihydroisoquinolines and 4,4-difluorotetrahydroisoquinolines has been developed. The procedure involves a silver-catalyzed intramolecular aminofluorination of alkyne. This one-pot reaction provides an efficient way to synthesize various fluorinated isoquinolines.
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