期刊
ORGANIC LETTERS
卷 15, 期 6, 页码 1338-1341出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol400280b
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资金
- Cambridge Commonwealth Trust
- Tertiary Education Commission of New Zealand
The stereocontrolled synthesis of a fully elaborated C1-11 subunit of madeirolide A is described, utilizing an asymmetric boron aldol reaction and a cis-selective hetero-Michael cyclization to form the tetrahydropyran ring, followed by efficient formation of the required C5 alpha-glycoside.
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