期刊
ORGANIC LETTERS
卷 15, 期 7, 页码 1448-1451出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol400136y
关键词
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资金
- Ministerio de Ciencia e Innovacion [CTQ2008-05409-C02-01, CTQ2011-22649, CSD2007-00006]
- DURSI-Generalitat de Catalunya [2009SGR-1441]
- Ramon y Cajal contract
- FPI
A stereoselective synthesis of L-carbidopa in seven steps and 50% overall yield from commercial compounds is described. The key step involves a highly enantloselective alpha-amlnation reaction of an acyclic beta-ketoester with di-tert-butyl azodicarboxylate induced by europium and (R,R)-dlphenyl-pybox.
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