期刊
ORGANIC LETTERS
卷 15, 期 19, 页码 5072-5075出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol402428e
关键词
-
资金
- Dow Chemical
- NSF [CHE-1048642, CHE-9304546]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1048642] Funding Source: National Science Foundation
Efficient aerobic oxidative methyl esterification of primary alcohols has been achieved with a heterogeneous catalyst consisting of 1 mol % Pd/charcoal (5 wt %) in combination with bismuth(III) nitrate and tellurium metal. The Bi and Te additives significantly increase the reaction rate, selectivity, and overall product yields. This readily accessible catalyst system exhibits a broad substrate scope and Is effective with both activated (benzylic) and unactivated (aliphatic) alcohols bearing diverse functional groups.
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