期刊
ORGANIC LETTERS
卷 14, 期 22, 页码 5756-5759出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302586m
关键词
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资金
- Major Basic Research Development Program [2011CB808700]
- National Natural Science Foundation of China [21032007, 21002113, 21121062]
- Chinese Academy of Sciences
- Technology Commission of Shanghai Municipality
- Croucher Foundation of Hong Kong
A new synthetic strategy to access polysubstituted furans regiospecifically has been developed using simple bicyclic alkenes and terminal ynones as starting materials with palladacycles as unique active catalysts. A rational mechanism has also been proposed. This reaction features mild reaction conditions, easily available starting materials and palladacycle catalysts, a wide substrate scope, and high regiospecificity.
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