期刊
ORGANIC LETTERS
卷 14, 期 21, 页码 5502-5505出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302584y
关键词
-
资金
- Midcareer Researcher Program [NRF-2011-0029186]
- Priority Research Centers Program [NRF-2012-1040282]
- WCU program [R31-2008-10029]
New phenothiazine based organic dyes were prepared for visible-light-driven organic transformations. The 3,7-disubstituted phenothiazine derivatives showed visible light absorption and reversible one-electron oxidation behavior. In the presence of 0.5 mol % of 3,7-disubstituted phenothiazines, primary benzylamines showed oxidative coupling under visible light irradiation from a blue LED. The electronic effect of substituents in phenothiazine dyes was observed in catalytic activities. The mechanistic pathway of oxidative coupling was discussed based on the detection of H2O2 after the reaction.
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