期刊
ORGANIC LETTERS
卷 14, 期 4, 页码 1066-1069出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol2031729
关键词
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资金
- Japan Society for the Promotion of Science (JSPS)
- Daiichi Sankyo Co., Ltd.
- Kyoto University
- University of Tokyo
- Grants-in-Aid for Scientific Research [23685020, 22106524] Funding Source: KAKEN
An efficient and high-yielding cross-coupling reaction of various primary, secondary, and tertiary alkyl chlorides with aryl Grignard reagents was achieved by using catalytic amounts of N-heterocyclic carbene ligands and iron salts. This reaction is a simple and efficient arylation method having applicability to a wide range of industrially abundant chloroalkanes, including polychloroalkanes, which are challenging substrates under conventional cross-coupling conditions.
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