期刊
ORGANIC LETTERS
卷 14, 期 12, 页码 3170-3173出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol301268j
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资金
- Research and Innovation Plan for Graduate Students of Jiangsu Higher Education Institutions [CXZZ11_0266]
- NSF [CHE-1009038, MRI CHE-0922366]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1009038] Funding Source: National Science Foundation
The preparation, X-ray structure, and reactivity of new, highly soluble, and reactive iodonium ylides derived from malonate methyl ester and bearing an ortho substituent on the phenyl ring are reported. These new reagents show higher reactivity than common phenyliodonium ylides in the Rh-catalyzed cyclopropanation, C-H insertion, and transylidation reactions under homogeneous conditions.
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