期刊
ORGANIC LETTERS
卷 14, 期 24, 页码 6134-6137出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302696e
关键词
-
资金
- National Natural Science Foundation of China [21072100, 21121002, 21272119]
A new phosphine-triggered tandem [3 + 4] annulation reaction between Morita-Baylis-Hillman carbonates and 1,4-diheteroatom dinucleophiles has been developed, which provides a facile synthetic method for saturated seven-membered 1,4-heterocycles such as 1,4-oxazepanes, 1,4-thiazepanes, and 1,4-diazepanes. Mechanistic investigation implies that this reaction takes place through a phosphine-catalyzed allylic alkylation followed by a general base-catalyzed intramolecular Michael cyclization.
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