期刊
ORGANIC LETTERS
卷 15, 期 1, 页码 220-223出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol303312p
关键词
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资金
- ICIQ Foundation
- MICINN [CTQ2010-15513]
- European Research Council [278541]
- European Union [273088]
- European Research Council (ERC) [278541] Funding Source: European Research Council (ERC)
- ICREA Funding Source: Custom
The enantioselective direct vinylogous aldol reaction of 3-methyl 2-cyclohexen-1-one with alpha-keto esters has been developed. The key to success was the design of a bifunctional primary amine-thiourea catalyst that can combine H-bond-directing activation and dienamine catalysis. The simultaneous dual activation of the two reacting partners results in high reactivity while securing high levels of stereocontrol.
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