期刊
ORGANIC LETTERS
卷 14, 期 6, 页码 1456-1459出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3001969
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资金
- Swedish Research Council (Vetenskapsradet)
- Wenner-Gren Foundation
- Swedish Governmental Agency for Innovation Systems (VINNOVA)
- Berzelii Center EXSELENT
A readily available pincer ruthenium(II) complex catalyzes the selective monoalkylation of (hetero)aromatic amines with a wide range of primary alcohols (including pyridine-, furan-, and thiophene-substituted alcohols) with high efficiency when used in low catalyst loadings (1 mol %). Tertiary amine formation via polyalkylation does not occur, making this ruthenium system an excellent catalyst for the synthesis of sec-amines.
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