期刊
ORGANIC LETTERS
卷 14, 期 23, 页码 5980-5983出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3028847
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- ICSN
- CNRS
- Government of China
Mono-N-arylation of benzamidines 1 with aryl boronic acids 2 was effectively achieved in the presence of a catalytic amount of Cu(OAc)(2) and NaOPiv under mild aerobic conditions. Combining this step with an intramolecular direct C-H bond functionalization, catalyzed by the same catalytic system but under oxygen at 120 degrees C, afforded benzimidazoles 3 in good to excellent yields.
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