期刊
ORGANIC LETTERS
卷 14, 期 20, 页码 5326-5329出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3025082
关键词
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资金
- Global COE Program of the Japan Society for the Promotion of Science (JSPS)
- University of Tokyo
- MEXT Japan
- NEDO
A simple and straightforward method for the preparation of indole-3-carboxylic acids was discovered through the direct carboxylation of indoles with atmospheric pressure of carbon dioxide (CO2) under basic conditions. The key for the reaction was found to be the use of a large excess of LiO'Bu as a base to suppress the undesired decarboxylation side reaction.
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