期刊
ORGANIC LETTERS
卷 14, 期 8, 页码 2184-2187出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3008183
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资金
- NSF [0844931]
- NIH [R01HL088559]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0844931] Funding Source: National Science Foundation
A reaction based fluorescence turn-on strategy for hydrogen sulfide (H2S) was developed. This strategy was based on a H2S-specific Michael addition-cyclization sequence. Other biological thiols such as cysteine and glutathione did not pursue the reaction and therefore did not turn on the fluorescence/consume the substrates. The probes showed good selectivity and sensitivity for hydrogen sulfide.
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