期刊
ORGANIC LETTERS
卷 14, 期 9, 页码 2210-2213出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol300418h
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-
资金
- National Natural Science Foundation of China [21072148]
The reaction of phenyliodine bis(trifluoroacetate) (PIFA) with a series of anilides 1 (E = CO2Et) In CF3CH2OH was found to give 3-hydroxy-2-oxindole derivatives 2, while that with various anilides 1' (E = CON(R-4)Ar) afforded the C-2-symmetric or unsymmetric spirooxindoles 3. These processes feature a metal-free oxidative C(sp(2))-C(sp(3)) bond formation, followed by oxidative hydroxylation or spirocyclization.
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