期刊
ORGANIC LETTERS
卷 14, 期 20, 页码 5314-5317出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302494n
关键词
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资金
- NIH-NIGMS [R01GM080269-01]
- Amgen
- Abbott
- Boehringer Ingelheim
- Caltech
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- NIH [RR027690]
Isocyanates, isothiocyanates, and carbodiimides are effective substrates in (3 + 2) cycloadditions with donor-acceptor cyclopropanes for the synthesis of five-membered heterocycles. These reactions exhibit a broad substrate scope, high yields, and well-defined chemoselectivity. Discussed herein are the implications of Lewis acid choice on the stereochemical outcome and the reaction mechanism.
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