期刊
ORGANIC LETTERS
卷 14, 期 13, 页码 3312-3315出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3012869
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Japan Society for the Promotion of Science
- Grants-in-Aid for Scientific Research [23350046] Funding Source: KAKEN
By use of 2-deuterated benzothiazoline as a deuterium donor in combination with a chiral phosphoric acid, the transfer deuteration of ketimine and alpha-iminoester took place smoothly to give alpha-deuterated amines in high yields with excellent enantioselectivities. The remarkable kinetic isotope effect suggests that carbon-deuterium bond cleavage is the rate-determining step.
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