期刊
ORGANIC LETTERS
卷 14, 期 7, 页码 1692-1695出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3002442
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资金
- National Natural Science Foundation of China [20902076, 21172185]
- Hunan Provincial Natural Science Foundation of China [11JJ1003]
- New Century Excellent Talents in University from Ministry of Education of China [NCET-11-0974]
- Undergraduate Investigated-Study and Innovated Experiment Plan of Hunan Province
The first palladium-catalyzed diarylamine formation from nitroarenes and cyclohexanone derivatives using borrowed hydrogen is described. Various diarylamines were selectively obtained in good to excellent yields. The reaction tolerated a wide range of functionalities. The nitro reduction, cyclohexanone dehydrogenation, and imine formation and reduction were realized in a cascade without an external reducing reagent and oxidant.
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