期刊
ORGANIC LETTERS
卷 14, 期 20, 页码 5358-5361出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302548c
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资金
- NIEHS NIH HHS [R01 ES016042] Funding Source: Medline
Two new ellagitannins containing a rare 3-oxo-1,3,3a,8b-tetrahydrofuro[3,4-b]benzofuran moiety, namely punicatannins A (1) and B (2), were isolated from pomegranate (Punica granatum) flowers. Their structures with absolute configuration were determined by detailed analysis of spectroscopic data, electronic circular dichroism (ECD) calculation, and chemical hydrolysis. A plausible biogenetic route involving a key enzymatic 1,4-Michael addition is proposed. Punicatannin A showed potent inhibition of alpha-glucosidase and lipogenic gene expression.
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