期刊
ORGANIC LETTERS
卷 14, 期 13, 页码 3558-3561出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol301635x
关键词
-
资金
- American Chemical Society Petroleum Research Fund [47598-GB3]
- Cambridge Isotope Laboratories, Inc.
- Research Corporation for Science Advancement
- M. J. Murdock Charitable Trust
The iridium-catalyzed arene C-H borylation reaction of benzylic amines has been developed, which inverts the typical steric-controlled product distribution to provide ortho-substituted boronate esters. Picolylamine was found to be an ideal ligand to replace 4,4'-di-tert-butylbipyridine to induce the directing effect. Preliminary experiments are consistent with a mechanism involving dissociation of one amine of the hemilabile diamine ligand.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据