期刊
ORGANIC LETTERS
卷 14, 期 14, 页码 3600-3603出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol301305p
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-
资金
- German Research Council DFG [IRTG 1038]
The NADPH-dependent tetrahydroxynaphthalene reductase (T4HNR) from Magnaporthe grisea was used for the biomimetic synthesis of (R)-GTRI-02 by stereoselective reduction of 1-(3,6,8-trihydroxy-1-methylnaphthalen-2-yl)ethanone. This also led to the isolation of a (3S,4R)-cis-ketodiol formed by T4HNR-catalyzed reduction of the corresponding hydroxynaphthoquinone. Flaviolin and lawsone also reduced to corresponding cis-ketodiols in good yields.
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