期刊
ORGANIC LETTERS
卷 14, 期 20, 页码 5294-5297出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302438z
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资金
- Department of Science and Technology (DST), New Delhi [SR/S1/OC-79/2009]
- Department of Biotechnology (DBT) [BT/P/RC/03]
- CSIR
An unprecedented aroylation at the ortho C-H bond with respect to a directing group has been accomplished via a Pd(II)-catalyzed cross dehydrogenative coupling approach using alkylbenzene as the synthetic equivalent of an aroyl moiety. The reaction proceeds through sequential C-C and C-O bond making at the expense of four consecutive C-H bond cleavages (three sp(3) benzylic C-H's and one sp(2) arene C-H) to selectively install an aroyl functionality at the proximal site of substrates containing various directing groups.
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