期刊
ORGANIC LETTERS
卷 14, 期 15, 页码 3955-3957出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol301962e
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资金
- National University of Singapore [R-143-000-469-112]
- GSK-EDB [R-143-000-491-592]
- Ministry of Education (MOE) of Singapore [R-143-000-494-112]
A stereoselective allylic alkylation of isatin-derived Morita-Baylis-Hillman (MBH) carbonates with nitroalkanes has been developed. In the presence of 10 mol % beta-isocupreidine (beta-ICD), 3,3'-disubstituted oxindoles were prepared with moderate diastereoselectivities and excellent enantioselectivities.
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