期刊
ORGANIC LETTERS
卷 14, 期 18, 页码 4714-4717出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol301781u
关键词
-
资金
- National Institute of Health [R01GM065515]
- Welch Foundation [F-1151]
- NSF [CHE-1212971]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1212971] Funding Source: National Science Foundation
A reversible covalent bond exchange of thiols, beta-sulfido-alpha,beta-unsaturated carbonyls, and dithianes has been studied in DMSO and D2P/DMSO mixtures. The equilibrium between thiols and beta-sulfido-alpha,beta-unsaturated carbonyls is obtained within a few hours, while the equilibration starting with the beta-dithiane carbonyls and thiols requires a few days. This time scale makes the system ideal for utilization in dynamic combinatorial chemistry.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据