4.8 Article

Catalyst-Free Intramolecular Oxidative Cyclization of N-Allylbenzamides: A New Route to 2,5-Substituted Oxazoles

期刊

ORGANIC LETTERS
卷 14, 期 18, 页码 4766-4769

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AMER CHEMICAL SOC
DOI: 10.1021/ol302031z

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  1. National Natural Science Foundation of China [21102071]
  2. Fundamental Research Funds for the Central Universities [1107020522, 1082020502]

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A catalyst-free intramolecular oxidative cyclization reaction of N-allylbenzamides has been developed to prepare 2,5-disubstituted oxazoles with good yields. This reaction gives an efficient synthetic strategy to form an oxazole nucleus directly from easily accessible substrates under temperate conditions.

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