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卷 14, 期 18, 页码 4930-4933出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302256y
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- NSC, Taiwan [NSC-100-2113-M-037-011]
A novel, concise and efficient synthesis of substituted isocoumarins is disclosed. o-Allylbenzaldehydes prepared from isovanillin were mediated by PdCl2-CuCl2 in water to undergo a domino reaction sequence, including 6-exo-trig cyclization, the addition of water, the elimination of PdHCl, the isomerization of carbon-carbon double bond, the oxidation of hemiacetals with the elimination of PdHCl, and regeneration of PdCl2 in situ to yield a series of new substituted isocoumarins in high yields, in one pot.
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