期刊
ORGANIC LETTERS
卷 14, 期 17, 页码 4318-4321出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302112q
关键词
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资金
- Junta de Andalucia [P07-FQM-02745]
- MICINN [CTQ2011-24502]
The complex (IPr)Ni(allyl)Cl (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolidene) catalyzes the cross-coupling reactions of heteroaromatic chlorides with aryl Grignard reagents. Catalyst loadings as low as 0.1 mol % have been used to afford the products in excellent yields. This nickel-based catalytic system also promotes the activation of the C-Ar-O bond of anisoles in the Kumada-Tamao-Corriu reaction under fairly mild conditions.
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