期刊
ORGANIC LETTERS
卷 14, 期 15, 页码 3882-3885出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol301608m
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Science Research Promotion Fund
- Network Joint Research Center for Materials and Devices
- Grants-in-Aid for Scientific Research [23245032, 20108004, 23655090] Funding Source: KAKEN
A convenient method for the synthesis of tetraalkylanthracenes and -pentacenes by means of ruthenium-catalyzed regioselective C-H alkylation of the corresponding acenequinones was developed. Dialkyldiarylpentacene was also synthesized using chemoselective tandem C-H alkylation/C-O arylation of dimethoxypentacenequinone. It was suggested that a tetraallrylpentacene is stable under air in the dark and possesses an appropriate HOMO level as active material for p-type organic field-effect transistors (OFETs).
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