期刊
ORGANIC LETTERS
卷 14, 期 3, 页码 914-917出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol203428c
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-
资金
- National Institutes of Health [GM-64444, 1P50 GM-086145]
A one-pot synthesis of dihydrobenzosiloles from styrenes has been developed. The reaction involves the nickel-catalyzed hydrosilylation of styrene with diphenylsilane, followed by the iridium-catalyzed dehydrogenative cyclization. This method is efficient for both electron-rich and -deficient styrenes and exhibits good functional group tolerance, as well as excellent regioselectivity. The forming dihydrobenzosiloles can be efficiently converted into valuable benzosiloles or 2-hydroxyphenethyl alcohols.
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