期刊
ORGANIC LETTERS
卷 14, 期 8, 页码 2154-2157出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol300676w
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资金
- Singapore National Research Foundation
- Singapore Economic Development Board (EDB)
- GlaxoSmithKline (GSK)
- Nanyang Technological University (NTU)
The first N-Heterocyclic Carbene (NHC) mediated activation of stable carboxylate esters to generate enolate intermediates is disclosed. The catalytically generated arylacetic ester enolates undergo enantioselective reactions with alpha,beta-unsaturated imines.
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