期刊
ORGANIC LETTERS
卷 14, 期 14, 页码 3708-3711出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol3015545
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资金
- UMBC
Nonsymmetrical, multifunctional bacteriochlorin derivatives possessing different substituents at the beta-pyrrolic positions have been prepared by stepwise, selective functionalization of 3,13-dibromo-5-methoxybacteriochlorin via palladium-coupling reactions. The new derivatives reported here include monovalent bioconjugatable bacteriochlorin, orthogonally protected bacteriochlorin amino acid, and push-pull bacteriochlorins. Taken together, this study provides a route to previously unavailable bacteriochlorin architectures for fundamental studies and diverse applications.
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