期刊
ORGANIC LETTERS
卷 15, 期 1, 页码 184-187出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol303186j
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资金
- Ligue Nationale Contre le Cancer
The straightforward synthesis of a double-lasso macrocycle from a nonsymmetrical [c2]daisy chain, using the copper(I)-catalyzed Huisgen alkyne-azide 1,3-dipolar cycloaddition, is described. The preparation of the nonsymmetrical alkyne azide [c2]daisy chain precursor was realized in situ via the exchange of the monomers contained in both symmetrical alkyne and azide [c2]daisy chains and was followed by mass spectrometry.
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