期刊
ORGANIC LETTERS
卷 14, 期 21, 页码 5542-5545出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302646a
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- University of Toronto
A one-pot synthesis of the chiral dihydrobenzofuran framework is described. The method utilizes Rh-catalyzed asymmetric ring opening (ARO) and Pd-catalyzed C-O coupling to furnish the product in excellent enantioselectivity without isolation of intermediates. Systematic metal-ligand studies were carried out to investigate the compatibility of each catalytic system using product enantiopurity as an indicator.
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