期刊
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卷 14, 期 22, 页码 5796-5799出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol302890a
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资金
- National Natural Science Foundation of China [21262024]
- Key Project of Chinese Ministry of Education [211193]
- 100 Talents Program of Ningxia
- Natural Science Foundation of Ningxia [NZ1043, NZ1165]
- National Basic Research Program 973 of China [2010CB534916]
- 211 Project in Ningxia University [ndzr09-1]
The first intramolecular Schmidt reaction of acyl chlorides with alkyl azides has been developed. In this one-pot conversion, an omega-azido hydrocinnamic acid is converted to a tricyclic lactam. The most important feature of the process is the efficiency in bond formation (one bond broken and three new bonds created) and ring construction (two new rings formed).
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